This study evaluates the mechanical performance of a metakaolin-based geopolymer matrix reinforced with quartz particles and polypropylene fibers, in comparison with a Portland cement-based matrix. Compressive strength, shrinkage, and flexural strength tests reveal that incorporating 20 wt% quartz particles significantly improves the mechanical properties of both matrices. The combined use of quartz particles and fibers contributes to shrinkage crack control and dimensional stability through synergistic effects involving particle–matrix interactions, fiber–matrix bonding, fiber surface characteristics, and toughening mechanisms. In the geopolymer matrix, the reinforcement effect of quartz particles is more pronounced due to the formation of a strong and chemically active interfacial bond. Compared with Portland cement composites, quartz particles increase the flexural and compressive strengths of geopolymer composites by approximately 2.5 and 1.3 times, respectively. The addition of 0.5 wt% polypropylene fibers slightly reduces strength but enhances energy absorption and alters the failure mode from brittle to more ductile. Overall, the results highlight the role of fibers in suppressing or arresting brittle fracture in cementitious and geopolymeric composites.
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• Geopolymer shows denser and more uniform microstructure than cement.
• Adding 20 wt% quartz improves strength and reduces shrinkage.
• Polypropylene fibers enhance toughness but slightly lower strength.
• Geopolymer has 21% higher compressive strength than cement composite.